More explanation to come later.
I need to emphasize that you should remove as many components as you can. It will only make things easier later on. At minimum, I recommend removing the A/C compressor, power steering pump, alternator, and water pump, along with all the mounting brackets for the individual components. Removing the radiator is also recommended. Obviously removing the fan and fan shroud are required. When you have all these removed, you should have plenty of room to work, as shown here:
This is the crankshaft pulley. You'll need to remove it with a special tool, called a "puller." (Ingenious name, right?)
This is the bolt in the center of the crankshaft pulley. You'll need to remove this before you attempt to pull off the pulley itself. It will be extremely difficult to remove. As of this writing, I have yet to get mine taken off. I've tried brute force as well as using a breaker bar and standing on it (I'm 230 lb.) I've even tried using an impact wrench. So far it hasn't budged. My plan is to remove the starter from underneath the motor and wedge a bar in the teeth to effectively "seize" the motor. Once I know the crankshaft pulley won't be able to spin under the torque, I'll do it MacGyver style - put a 6-foot steel pipe over the end of the breaker bar and hang off the end of it. It's been awhile since my last physics class, but my calculations estimate the amount of force that I could apply with a 6-ft lever at 16963.929 ft-lbs. I somehow doubt I'll need to exert all of my 230 lbs to remove the bolt, don't you?